Science Watch® - Tracking Trends and Performance in Basic Research
January/February 2005


Water Makes CoO2 a New Superconductor
by Simon Mitton
WHAT'S HOT IN
P H Y S I C S
Rank      Paper Citations This Period (Jul-Aug 04) Rank Last Period (May-Jun 04)
1 D.N. Spergel, et al., "First-year Wilkinson Microwave Anisotropy Probe (WMAP) observations: Determination of cosmological parameters," Astrophys. J. Suppl. Ser., 148(1): 175-94, September 2003. [6 U.S. and Canadian institutions] *715BR 144 1
2 C.L. Bennett, et al., "First-year Wilkinson Microwave Anisotropy Probe (WMAP) observations: Preliminary maps and basic results," Astrophys. J. Suppl. Ser., 148(1): 1-27, September 2003. [7 U.S. and Canadian institutions] *715BR 82 2
3 K. Eguchi, et al., "First results from KamLAND: Evidence for reactor antineutrino disappearance," Phys. Rev. Lett., 90(2): 1802, 17 January 2003. [12 institutions worldwide] *636FP 50 4
4 T. Nakano, et al., "Evidence for a narrow S = +1 baryon resonance in photoproduction from the neutron," Phys. Rev. Lett., 91(1): 2002, 4 July 2003. [19 institutions worldwide] *696YP 24
5 K. Takada, et al., "Superconductivity in two-dimensional Co02 layers," Nature, 422(6927): 53-5, 6 March 2003. [Natl. Inst. Materials Sci., Tsukuba, Japan; CREST, Japan Sci. Tech. Corp.] *651VP 24 10
6 J. Hjorth, et al., "A very energetic supernova associated with the d-ray burst of 29 March 2003," Nature, 423[6942]: 847-50, 19 June 2003. [13 institutions worldwide] *691BQ 22 9
7 K.Z. Stanek, et al., "Spectroscopic discovery of the supernova 2003dh associated with GRB 030329," Astrophys. J., 591(1): L17-20, 1 July 2003. [11 institutions worldwide] *691QZ 22
8 R.R. Caldwell, "A phantom menace? Cosmological consequences of a dark energy component with super-negative equation of state," Phys. Lett. B, 545(1,2): 23-9, 3 October 2002. [Dartmouth Coll., Hanover, NH] *606WN 22
9 V.V. Barmin, et al. (the DIANA Collaboration), "Observation of a baryon resonance with positive strangeness in K+ collisions with Xe nuclei," Phys. Atom. Nuclei., 66(9): 1715-8, September 2003. [Inst. Theor. Exp. Physics, Moscow, Russia; IFN, Italy] *730XH 21
10 M. Greiner, C.A. Regal, D.S. Jin, "Emergence of a molecular Bose-Einstein condensate from a Fermi gas," Nature, 426(6966): 537-40, 4 December 2003. [NIST, U. Colorado, Boulder] 20
 SOURCE: Thomson Scientific Hot Papers DatabaseRead  the Legend.

After a prolonged absence, superconductivity has returned to the Physics Top Ten. Paper #5 announces the discovery of superconductivity in CoO2 when arranged as a layered compound. In superconductivity a substance loses electrical resistivity when cooled below a "critical temperature," Tc. Almost all metals become superconducting at very low temperatures. In 1986 "superconductivity fever" broke out in physics laboratories worldwide following the discovery that CuO compounds, or cuprates, are superconductors at relatively high temperatures when compared to metals. Within a year researchers found that the ceramic superconductor YBCO makes the transition above the temperature of liquid nitrogen. For many years researchers have tried without success to find superconducting compounds based on the oxides of elements close to copper in the periodic table. This fruitless search has ended with #5, which describes the discovery of superconductivity in sodium cobalt oxyhydrate, a compound with Tc=5K.

At Japan’s National Institute for Materials Science, Takayoshi Sasaki and colleagues created the superconductor from layers of cobalt oxide separated by Na+ ions and H2O. The new superconductor is unusual in containing H2O, which has the effect of doubling the interlayer distance to 2 nm. This appears to be essential to triggering the superconducting behavior. The crystal structure of the oxyhydrate has some similarities to the hexagonal structure displayed by superconducting MgB2.

The citation rate of #5 is being boosted by a technical development announced at Brookhaven National Laboratory early in 2004. Sangmoon Park, a chemist at Brookhaven, has devised a safe method of making the superconductor. His research has eliminated processes requiring volatile and inflammable liquids that produce much hazardous waste. His procedure uses plain water! (S. Park, et al., Phys. Rev. B, 68[18]: art. no. 180505, 2003.) The new synthesis process will be helpful in developing real-world applications because water-based superconductors are expected to be more versatile. Metal superconductors are brittle and cannot be made into pliable objects.

The Top Ten this period has a second paper #10 on low-temperature physics, which describes a truly remarkable way to make a molecular Bose-Einstein condensate (BEC). The starting point for the experiment, conducted at NIST (Boulder, Colorado), is the production of an ultracold degenerate gas of 40K through laser trapping and evaporative cooling. This atomic gas obeys Fermi statistics. Markus Greiner and colleagues then used a magnetic field to tune the atom-atom interactions in this gas in such a way that atom pairs are converted to weakly bound 40K2 molecules. Critically, the survival time of the molecules can be much longer than the collision time in the gas. The NIST researchers observed a bimodal momentum distribution among these molecules, following which the phase transition to BEC occurred. Currently there are experiments running in several labs to unlock the physics of mixtures of BEC and Fermi gases at nanoKelvin temperatures, with a view to tuning the system continuously between the two limits of BEC and Fermi gas.

An enduring mystery in observational astronomy is the origin of gamma-ray bursts (GRBs), first noticed in the 1960s. Since 1997, the BeppoSAX satellite has provided rapid and accurate positions for several GRBs a year. Optical astronomers have seized on these prized coordinates to observe the faint afterglows, and thereby measure the redshifts, which establish that GRBs are at cosmological distances. The afterglow phenomenon suggests that at least some GRBs are associated with the core collapse of massive stars. However, direct evidence of a link between a supernova explosion and a GRB has been hard to secure. That’s because GRBs are typically at a redshift z ~ 1, which is too distant for obtaining a good spectrum of the accompanying star.

On March 29, 2003, the situation changed dramatically when the High Energy Transient Explorer II satellite registered an extremely intense GRB lasting 25s. This produced a bright afterglow which a host of ground-based telescopes observed for several weeks. By the end of the first week, the spectroscopic campaign led by Tom Matheson (Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts) began to see light from an underlying supernova emerge, and with the passing days this became more prominent. The subtraction of the continuum from the afterglow left a spectrum typical of a hypernova, a powerful supernova with high ejection speed. This category of exploding star arises as a result of sudden and catastrophic collapse of the core of a massive star. Hot Paper #7 provides the first solid evidence of a direct link between a gamma-ray burst and a hypernova collapse.end

Dr. Simon Mitton is a Fellow of St. Edmund’s College, University of Cambridge.

Science Watch®, January/February 2005, Vol. 16, No. 1
Citing URL: http://www.sciencewatch.com/jan-feb2005/sw_jan-feb2005_page6.htm

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