"Fast mass transport through sub-2-nanometer carbon
nanotubes," by Jason K. Holt and 7 others, Science,
312(5776): 1034-7, 19 May 2006.
[Authors' affiliations: Lawrence Livermore National Laboratory, CA;
University of California, Berkeley]
Abstract: "We report gas and water flow measurements
through microfabricated membranes in which aligned carbon nanotubes with
diameters of less than 2 nanometers serve as pores. The measured gas flow
exceeds predictions of the Knudsen diffusion model by more than an order of
magnitude. The measured water flow exceeds values calculated from continuum
hydrodynamics models by more than three orders of magnitude and is
comparable to flow rates extrapolated from molecular dynamics simulations.
The gas and water permeabilities of these nanotube-based membranes are
several orders of magnitude higher than those of commercial polycarbonate
membranes, despite having pore sizes an order of magnitude smaller. These
membranes enable fundamental studies of mass transport in confined
environments, as well as more energy-efficient nanoscale filtration."
This 2006 report from Science was cited 16
times in current journal articles indexed by Clarivate
during March-April 2008. During that two-month period, no other chemistry
paper, aside from reviews, garnered a higher citation total. Prior to the
most recent bimonthly count, citations to the paper have accrued as
follows:
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