Science Watch® - Tracking Trends and Performance in Basic Research
September/October 2004


ZnO Nanorods and Degenerate Fermi Gas Enliven Quantum Physics
by Simon Mitton
WHAT'S HOT IN PHYSICS
Rank      Paper Citations This Period (Mar-Apr 04) Rank Last Period (Jan-Feb 04)
1 D.N. Spergel, et al., "First-year Wilkinson Microwave Anisotropy Probe (WMAP) observations: Determination of cosmological parameters," Astrophys. J. Suppl. Ser., 148(1): 175-94, September 2003. [6 U.S. and Canadian institutions] *715BR
(Also read comments by Verde, L; co-author of this Hot Paper.)
105 1
2 C.L. Bennett, et al., "First-year Wilkinson Microwave Anisotropy Probe (WMAP) observations: Preliminary maps and basic results," Astrophys. J. Suppl. Ser., 148(1): 1-27, September 2003. [7 U.S. and Canadian institutions] *715BR 50 2
3 K. Eguchi, et al., "First results from KamLAND: Evidence for reactor antineutrino disappearance," Phys. Rev. Lett., 90(2): 1802, 17 January 2003. [12 institutions worldwide] *636FP 34 3
4 Q.R. Ahmad, et al., "Direct evidence for neutrino flavor transformation from neutral-current interactions in the Sudbury Neutrino Observatory," Phys. Rev. Lett., 89(1): 1301, 1 July 2002. [17 institutions worldwide] *563YN 31 4
5 T. Nakano, et al., "Evidence for a narrow S = +1 baryon resonance in photoproduction from the neutron," Phys. Rev. Lett., 91(1): 2002, 4 July 2003. [19 institutions worldwide] *696YP 27 6
6 Q.R. Ahmad, et al., "Measurement of day and night neutrino energy spectra at SNO and constraints on neutrino mixing parameters," Phys. Rev. Lett., 89(1): 1302, 1 July 2002. [17 institutions worldwide] *563YN 23 5
7 D.C. Look,et al., "Characterization of homoepitaxial p-type ZnO grown by molecular beam epitaxy," Appl. Phys. Lett., 81(10): 1830-2, 2 September 2002. [Air Force Res. Lab., Wright-Patterson AFB, OH; Wright St. U., Dayton, OH; Eagle-Picher Technol., Miami, OK] *588 19
8 J. Hjorth, et al., "A very energetic supernova associated with the g-ray burst of 29 March 2003," Nature, 423[6942]: 847-50, 19 June 2003. [13 institutions worldwide] *691BQ 19
9 K.M. O’Hara, et al., "Observation of a strongly interacting degenerate Fermi gas of atoms," Science, 298(5601): 2179-82, 13 December 2002. [Duke U., Durham, NC] *624RA 17
10 W.I. Park, et al., "Metalorganic vapor-phase epitaxial growth of vertically well-aligned ZnO nanorods," Appl. Phys. Lett., 80(22): 4232-4, 3 June 2002. [Pohang U. Sci. Tech., Korea] *555BB 17
 SOURCE: Thomson Scientific Hot Papers DatabaseRead  the full legend.

Physicists are going to great lengths in their quest for semiconductor materials that can be used for blue and UV solid-state emitters and detectors. Blue lasers will find commercial applications in laser printers, and also for CD-ROM and DVD memories. The hunt is on for a suitable material that has good emissivity in blue light. Although most of the development so far has centered around GaN and GaN-based alloys, the brightest star is ZnO, a compound with high emissivity, low cost, and suitability for processing via wet chemistry. However, ZnO has a serious deficiency: the absence of good, reproducible p-type material, in which electrical conduction is through the movement of holes. Both p-type and n-type (conduction through electrons) materials are needed for the fabrication of transistors (p-n-p) and junctions (p-n).

Hot Paper #7 reports for the first time the successful growth of p-type ZnO films by molecular beam epitaxy, a discovery which opens the door to junctions and quantum wells based on ZnO. The new process first requires the fabrication of ZnO film, which is achieved by heating pure Zn to 450 – 700° C in a flow of research-grade O2. The team led by David Look (Wright State University, Dayton, Ohio) found that if a small amount of N2 is added to the gas flux, p-type ZnO films were deposited with a thickness of 1.9 mm. Laboratory study of these films showed that they have the appropriate electrical properties for junction fabrication.

The ZnO excitement continues with newcomer #10, which announces a spectacular breakthrough in the growth of ZnO nanorods. One-dimensional nanowires and nanorods are attracting huge interest because of their physical properties and their potential for application to a great diversity of electronic and photonic devices. The growth of nanowires requires impurities as catalysts to precipitate the formation of droplets for deposition on a preferred site. Unfortunately the catalyst can be unintentionally incorporated as a contaminant detrimental to device fabrication.

A completely new approach to nanorod growth is heralded in #10, in which a group of physicists based at Pohang University, South Korea, demonstrate a unique catalyst-free method of making ZnO nanorods. Their method of chemical vapor deposition can produce high-quality ZnO nanorods on a large scale at low cost. For Science Watch, Gyu-Chui Yi made the following comment: "Since our method does not need any metal catalyst it enables us to grow high-purity nanorods. The nanorods grown by our method are vertically aligned on the substrate and exhibit uniform thickness and length distributions." More recent publications from this group report the realization of a metal/semiconductor junction, nanodiode arrays, nanorod quantum structures, and light-emitting nanorod devices. Paper #10 opens a window on a new world of amazing quantum devices.

The quantum physics theme continues with #9, reporting the properties of a degenerate Fermi gas. Whatever is that? To answer this question we need to remember that the elementary constituents of matter are divided into fermions and bosons, both of which behave according to their angular momentum, or spin. Fermions have an intrinsic spin that is an odd multiple of the Planck constant whereas the bosons acquire an even multiple. The behavioral properties come from quantum statistics, which dictate that at ultracold temperatures, the properties of fermions and bosons are dramatically different.

In 1995 low-temperature physicists produced Bose-Einstein condensation (BEC) in which atoms with integer spins collapse to a common ground state. Making the fermionic cousin of BEC has proved immensely challenging because in Fermi-Dirac statistics the atoms are forbidden from occupying the same quantum states. John Thomas’s team at Duke University has become the first group in the world to create a Fermi gas that is degenerate, meaning that all the lowest quantum states are occupied. To achieve this they first designed a unique all-optical trap using a high-power CO2 laser, to create an invisible bowl for holding ultracold 6Li atoms. Evaporative cooling allows mK temperatures to be reached quickly, at which point strong interactions can be induced using a magnetic field.

Paper #9 showcases the bizarre behavior of fermionic 6Li atoms, which the CO2 laser cradles as a cigar-shaped cloud of atoms, 1 mm long and 0.1 mm wide. When the trap is suddenly switched off, the gas balloons along the transverse direction while staying motionless along the cigar axis. Ordinary gas would quickly assume a spherical shape. The anisotropy seen by the Duke researchers may be indicative of superfluidity. This laboratory realization of a strongly interacting Fermi gas provides a tabletop forum for checking the theory of more exotic fermionic matter, such as quark matter or the interiors of neutron stars.end 

Dr. Simon Mitton is the Senior Fellow of
St Edmund’s College, University of Cambridge,
U.K.

Science Watch®, September/October 2004, Vol. 15, No. 5
Citing URL: http://www.sciencewatch.com/sept-oct2004/sw_sept-oct2004_page6.htm

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